Advanced exercises

part 3

 

The half cells above were connected as shown in the diagram below.

a) In the cell constructed by the two half cells, what happens to the mass of each electrode?

b) From the information given, what order do the half cells appear in the electrochemical series?

c) If the half cell potential of is 0.33V what is the cell EMF of a cell constructed from the two half cells below?

Solution

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Balance for charge by adding electrons tot he most positive side. Balance for hydrogen by adding Hydrogen ions to the hydrogen deficient side. Balance for oxygen by adding water to the oxygen deficient side. Balance for Ag atoms Balance for oxygen by adding water to the oxygen deficient side. Balance for hydrogen by adding Hydrogen ions to the hydrogen deficient side. Balance for charge by adding electrons tot he most positive side. Home
Each oxygen atom has an oxidation number of -2 Each oxygen atom has an oxidation number of -2 Each potassium atom has an oxidation number of =1