|Re-purposing plastics (PLA)
Aim: In this part of the experiment you will take PLA cups and break them down by hydrolysis to form a antimicrobial cleaning solution of lactic acid.
1. Cut a PLA cup into small pieces using a scissors. The smaller the pieces, the faster the reaction. Do not use any coloured parts of the cup or the lip/bottom corners (thicker portions) of the cup.
2. Measure 5.0 grams of the PLA pieces and place them in a clean 250 mL Erlenmeyer flask.
|3. Measure 100 mL of the sodium hydroxide/ethanol solution and add it to the flask.
4. Add a magnetic stirrer to the flask.
5. Cover the flask with a watch glass to reduce evaporation, the watch glass will allow vapours of ethanol to vent when pressure builds up in the flask.
|6. Heat the solution to 90 oC while stirring. Remove from the hot-plate if the solution in the flask begins to boil.
7. Continue heating until all of the PLA has dissolved (This usually takes 10 minutes). Do not leave unattended.
8. Remove from hot plate and let it cool on the counter, then continue to cool the mixture in an ice bath
|9. Once cool, measure the pH of the solution using pH paper, universal indicator or pH probe. Acidify the mixture by slowly adding 2M hydrochloric acid in 1-2 mL additions until a pH of 4-5 is reached. The solution now contains lactic acid and sodium chloride.
|The universal indicator chart is used to adjust the addition of the 2M HCl .
The colour of the lactic acid solution should be compared to the chart shown on the right.
1. Consider the animation of the breakdown of polylactic acid (PLA) into its monomer form,as shown on the right.
a. What part does NaOH play in this reaction? Justify your answer.
b. What type of reaction is this? Justify your answer.
c. What type of reaction formed polylactic acid (PLA) from its monomers? Justify your answer.
d. Is PLA a type of polyester? Explain your reasoning.
e. Consider a single polyemric chain of lactic acid.
i. Draw thestructural formula of the repeating unit.
ii Find the molar mass of the repeating unit.
iii. Assuming that the 5.00 gram sample of PLA consists of only a single
f. Measure the volume of the final lactic acid solution using a measuring cylinder. Calculate the concentration, in mol/litre, of lactic acid in the solution.
2. What is lactic acid used for in the cosmetics industry?
|3. Why is lactic acid a key ingredient in household cleaners?
|4. Use your sample of lactic acid, that you have obtained from the plastic cups, to conduct an investigation into the antimicrobial properties of lactic acid solution.